Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation

We describe a Rh-catalyzed desymmetrization of all-carbon quaternary centers from α,α-bis(allyl)aldehydes by a cascade featuring isomerization and hydroacylation. This desymmetrization competes with two other novel olefin functionalizations that are triggered by C–H bond activation, including carboa...

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Detalles Bibliográficos
Autores principales: Park, Jung-Woo, Kou, Kevin G. M., Kim, Daniel K., Dong, Vy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4618402/
https://www.ncbi.nlm.nih.gov/pubmed/26508999
http://dx.doi.org/10.1039/c5sc01553g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4618402/
https://www.ncbi.nlm.nih.gov/pubmed/26508999
http://dx.doi.org/10.1039/c5sc01553g

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