Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

[Image: see text] Here we report a ternary catalyst system for the intramolecular hydroamidation of unactivated olefins using simple N-aryl amide derivatives. Amide activation in these reactions occurs via concerted proton-coupled electron transfer (PCET) mediated by an excited state iridium complex...

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Detalles Bibliográficos
Autores principales: Miller, David C., Choi, Gilbert J., Orbe, Hudson S., Knowles, Robert R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629195/
https://www.ncbi.nlm.nih.gov/pubmed/26439818
http://dx.doi.org/10.1021/jacs.5b09671

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629195/
https://www.ncbi.nlm.nih.gov/pubmed/26439818
http://dx.doi.org/10.1021/jacs.5b09671

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