Cargando…

Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

[Image: see text] Here we report a ternary catalyst system for the intramolecular hydroamidation of unactivated olefins using simple N-aryl amide derivatives. Amide activation in these reactions occurs via concerted proton-coupled electron transfer (PCET) mediated by an excited state iridium complex...

Descripción completa

Detalles Bibliográficos
Autores principales:	Miller, David C., Choi, Gilbert J., Orbe, Hudson S., Knowles, Robert R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2015
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629195/ https://www.ncbi.nlm.nih.gov/pubmed/26439818 http://dx.doi.org/10.1021/jacs.5b09671

Ejemplares similares

Catalytic defluorinative ketyl–olefin coupling by halogen-atom transfer
por: Bellotti, Peter, et al.
Publicado: (2022)

Ritter-enabled catalytic asymmetric chloroamidation of olefins
por: Steigerwald, Daniel C., et al.
Publicado: (2020)

A Practical and Catalytic Reductive Olefin Coupling
por: Lo, Julian C., et al.
Publicado: (2014)

Silylium ion migration dominated hydroamidation of siloxy-alkynes
por: Wang, Heng-Ding, et al.
Publicado: (2022)

Catalytic Enantioconvergent Couplings of Secondary and Tertiary Electrophiles with Olefins
por: Wang, Zhaobin, et al.
Publicado: (2018)

A General and Highly Selective Palladium‐Catalyzed Hydroamidation of 1,3‐Diynes
por: Liu, Jiawang, et al.
Publicado: (2020)

Computational study of the mechanism and selectivity of ruthenium-catalyzed hydroamidations of terminal alkynes
por: Maity, Bholanath, et al.
Publicado: (2015)

Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
por: Zhou, Zijun, et al.
Publicado: (2017)

Catalytic Hydrodifluoroalkylation of Unactivated Olefins
por: Yue, Wen-Jun, et al.
Publicado: (2022)

Catalytic olefin metathesis in blood
por: Nasibullin, Igor, et al.
Publicado: (2023)

Highly chemoselective synthesis of hindered amides via cobalt-catalyzed intermolecular oxidative hydroamidation
por: Yin, Yun-Nian, et al.
Publicado: (2021)

Enantioselective synthesis of α-aminoboronates by NiH-catalysed asymmetric hydroamidation of alkenyl boronates
por: Zhang, Yao, et al.
Publicado: (2022)

Biochemistry and Theory of Proton-Coupled Electron Transfer
por: Migliore, Agostino, et al.
Publicado: (2014)

Bioinspired desaturation of alcohols enabled by photoredox proton-coupled electron transfer and cobalt dual catalysis
por: Huang, Long, et al.
Publicado: (2022)

Electrochemical Deconstructive Functionalization of Cycloalkanols via Alkoxy Radicals Enabled by Proton-Coupled Electron Transfer
por: Hareram, Mishra Deepak, et al.
Publicado: (2022)

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis
por: Murray, Philip R. D., et al.
Publicado: (2021)

Simple, Chemoselective, Catalytic Olefin Isomerization
por: Crossley, Steven W. M., et al.
Publicado: (2014)

Z-Selective Catalytic Olefin Cross-Metathesis
por: Meek, Simon J., et al.
Publicado: (2011)

Enabling Molecular-Level Computational Description of Redox and Proton-Coupled Electron Transfer Reactions of Samarium Diiodide
por: Himmelstrup, Jonas, et al.
Publicado: (2023)

Correction to “Simple, Chemoselective, Catalytic Olefin Isomerization”
por: Crossley, Steven W. M., et al.
Publicado: (2015)

Catalytic, transannular carbonyl-olefin metathesis reactions
por: Riehl, Paul S., et al.
Publicado: (2019)

A Quinol Anion as Catalytic Intermediate Coupling Proton Translocation With Electron Transfer in E. coli Respiratory Complex I
por: Nuber, Franziska, et al.
Publicado: (2021)

Reactive Adsorption Desulfurization Coupling Olefin Conversion in Fluid Catalytic Cracking Gasoline Upgrading Process
por: Yang, Huanhuan, et al.
Publicado: (2023)

Proton-Coupled Electron Transfer Guidelines, Fair and Square
por: Tyburski, Robin, et al.
Publicado: (2021)

Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor
por: Wang, Peng, et al.
Publicado: (2022)

Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
por: Odella, Emmanuel, et al.
Publicado: (2020)

Cooperative activation of cyclobutanones and olefins leads to bridged-ring systems by a catalytic [4+2] coupling
por: Ko, Haye Min, et al.
Publicado: (2014)

Proton-Coupled Electron Transfer: Moving Together and Charging Forward
por: Hammes-Schiffer, Sharon
Publicado: (2015)

The Morita–Baylis–Hillman reaction for non-electron-deficient olefins enabled by photoredox catalysis
por: Li, Long-Hai, et al.
Publicado: (2022)

Proton-coupled electron transfer of macrocyclic ring hydrogenation: The chlorinphlorin
por: Sun, Rui, et al.
Publicado: (2022)

Proton-Coupled Electron Transfer at the Surface of Polyoxovanadate-Alkoxide Clusters
por: Proe, Kathryn R., et al.
Publicado: (2023)

Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins
por: Xin, Tiansi, et al.
Publicado: (2022)

Bonds over Electrons: Proton Coupled Electron Transfer at Solid–Solution Interfaces
por: Mayer, James M.
Publicado: (2023)

Concerted Electron-Nuclear Motion in Proton-Coupled Electron Transfer-Driven Grotthuss-Type Proton Translocation
por: Arsenault, Eric A., et al.
Publicado: (2022)

Solvent-modulated proton-coupled electron transfer in an iridium complex with an ESIPT ligand
por: Kim, Siin, et al.
Publicado: (2022)

Nonequilibrium Dynamics of Proton-Coupled Electron Transfer in Proton Wires: Concerted but Asynchronous Mechanisms
por: Goings, Joshua J., et al.
Publicado: (2020)

Stable Monoareno-pentalenes with Two Olefinic Protons
por: Mayer, Péter J., et al.
Publicado: (2022)

Catalytic Diamination of Olefins via N–N Bond Activation
por: Zhu, Yingguang, et al.
Publicado: (2014)

A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides
por: Neuhaus, James D., et al.
Publicado: (2018)

Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
por: Abbenseth, Josh, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_utff4h5h1eflkff75bl2r1ath0