Dependence of Vibronic Coupling on Molecular Geometry and Environment: Bridging Hydrogen Atom Transfer and Electron–Proton Transfer

[Image: see text] The rate constants for typical concerted proton-coupled electron transfer (PCET) reactions depend on the vibronic coupling between the diabatic reactant and product states. The form of the vibronic coupling is different for electronically adiabatic and nonadiabatic reactions, which...

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Detalles Bibliográficos
Autores principales: Harshan, Aparna Karippara, Yu, Tao, Soudackov, Alexander V., Hammes-Schiffer, Sharon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629534/
https://www.ncbi.nlm.nih.gov/pubmed/26412613
http://dx.doi.org/10.1021/jacs.5b07327

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629534/
https://www.ncbi.nlm.nih.gov/pubmed/26412613
http://dx.doi.org/10.1021/jacs.5b07327

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