Cargando…

Dependence of Vibronic Coupling on Molecular Geometry and Environment: Bridging Hydrogen Atom Transfer and Electron–Proton Transfer

[Image: see text] The rate constants for typical concerted proton-coupled electron transfer (PCET) reactions depend on the vibronic coupling between the diabatic reactant and product states. The form of the vibronic coupling is different for electronically adiabatic and nonadiabatic reactions, which...

Descripción completa

Detalles Bibliográficos
Autores principales:	Harshan, Aparna Karippara, Yu, Tao, Soudackov, Alexander V., Hammes-Schiffer, Sharon
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2015
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629534/ https://www.ncbi.nlm.nih.gov/pubmed/26412613 http://dx.doi.org/10.1021/jacs.5b07327

Ejemplares similares

Enhanced Rigidification within a Double Mutant of Soybean Lipoxygenase Provides Experimental Support for Vibronically Nonadiabatic Proton-Coupled Electron Transfer Models
por: Hu, Shenshen, et al.
Publicado: (2017)

Probing Nonadiabaticity in the Proton-Coupled Electron Transfer Reaction Catalyzed by Soybean Lipoxygenase
por: Soudackov, Alexander V., et al.
Publicado: (2014)

Proton-Coupled Electron Transfer: Moving Together and Charging Forward
por: Hammes-Schiffer, Sharon
Publicado: (2015)

Nonequilibrium Dynamics of Proton-Coupled Electron Transfer in Proton Wires: Concerted but Asynchronous Mechanisms
por: Goings, Joshua J., et al.
Publicado: (2020)

Kinetic model for reversible radical transfer in ribonucleotide reductase
por: Reinhardt, Clorice R., et al.
Publicado: (2022)

Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
por: Odella, Emmanuel, et al.
Publicado: (2020)

Hidden vibronic and excitonic structure and vibronic coherence transfer in the bacterial reaction center
por: Policht, Veronica R., et al.
Publicado: (2022)

Concerted Proton-Coupled Electron Transfer to a Graphite Adsorbed Metalloporphyrin Occurs by Band to Bond Electron Redistribution
por: Hutchison, Phillips, et al.
Publicado: (2023)

Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor
por: Nilsen-Moe, Astrid, et al.
Publicado: (2020)

Probing intramolecular vibronic coupling through vibronic-state imaging
por: Kong, Fan-Fang, et al.
Publicado: (2021)

Carotenoid-to-bacteriochlorophyll energy transfer through vibronic coupling in LH2 from Phaeosprillum molischianum
por: Thyrhaug, Erling, et al.
Publicado: (2017)

Computational Insights into Five- versus Six-Coordinate Iron Center in Ferrous Soybean Lipoxygenase
por: Yu, Tao, et al.
Publicado: (2016)

Vibronic coupling and ultrafast electron transfer studied by picosecond time-resolved resonance Raman and CARS spectroscopy
por: Wachsmann-Hogiu, S
Publicado: (2000)

Excited-state intramolecular proton transfer with and without the assistance of vibronic-transition-induced skeletal deformation in phenol–quinoline
por: Liu, Yu-Hui, et al.
Publicado: (2021)

Proton-coupled electron transfer of macrocyclic ring hydrogenation: The chlorinphlorin
por: Sun, Rui, et al.
Publicado: (2022)

Electrocatalytic NAD(+) reduction via hydrogen atom-coupled electron transfer
por: Liu, Fengyuan, et al.
Publicado: (2022)

Surface Hopping Dynamics on Vibronic Coupling Models
por: Zobel, J. Patrick, et al.
Publicado: (2021)

Concerted One-Electron Two-Proton Transfer Processes in Models Inspired by the Tyr-His Couple of Photosystem II
por: Huynh, Mioy T., et al.
Publicado: (2017)

Proton-assisted electron transfer and hydrogen-atom diffusion in a model system for photocatalytic hydrogen production
por: Zhang, Yuanzheng, et al.
Publicado: (2020)

Quantum coherence as a witness of vibronically hot energy transfer in bacterial reaction center
por: Paleček, David, et al.
Publicado: (2017)

Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role
por: Pascher, Tobias F., et al.
Publicado: (2019)

Electrochemically Tunable Proton‐Coupled Electron Transfer in Pd‐Catalyzed Benzaldehyde Hydrogenation
por: Koh, Katherine, et al.
Publicado: (2019)

The hydrogen atom transfer reactivity of sulfinic acids
por: Griesser, Markus, et al.
Publicado: (2018)

Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents
por: Wang, Dinghai, et al.
Publicado: (2019)

The Rational Design of Reducing Organophotoredox Catalysts Unlocks Proton-Coupled Electron-Transfer and Atom Transfer Radical Polymerization Mechanisms
por: Bortolato, Tommaso, et al.
Publicado: (2023)

Energy transfer in N-component nanosystems enhanced by pulse-driven vibronic many-body entanglement
por: Gómez-Ruiz, Fernando J., et al.
Publicado: (2023)

Oxygen-Atom Defect Formation in Polyoxovanadate Clusters via Proton-Coupled Electron Transfer
por: Schreiber, Eric, et al.
Publicado: (2022)

Efficient electron transfer across hydrogen bond interfaces by proton-coupled and -uncoupled pathways
por: Cheng, Tao, et al.
Publicado: (2019)

Estimation of Excited-State Geometries of Benzene and Fluorobenzene through Vibronic Analyses of Absorption Spectra
por: Köse, Muhammet Erkan
Publicado: (2022)

Vibronic effects accelerate the intersystem crossing processes of the through-space charge transfer states in the triptycene bridged acridine–triazine donor–acceptor molecule TpAT-tFFO
por: Kaminski, Jeremy M., et al.
Publicado: (2022)

Effect of a Solid-Hydrogen Environment on UV-Induced Hydrogen-Atom Transfer in Matrix-Isolated Heterocyclic Thione Compounds
por: Rostkowska, Hanna, et al.
Publicado: (2021)

Harnessing Proton-Coupled Electron Transfer for Hydrogenation of Aza-Arenes: Photochemistry of Quinoxaline Derivatives in Methanol
por: Morawski, Olaf W., et al.
Publicado: (2023)

Optimisation of CLIC transfer structure geometry to increase the beam coupling
por: Millich, Antonio
Publicado: (1994)

Biochemistry and Theory of Proton-Coupled Electron Transfer
por: Migliore, Agostino, et al.
Publicado: (2014)

Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides
por: Proctor, Rupert S. J., et al.
Publicado: (2021)

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation
por: Capaldo, Luca, et al.
Publicado: (2021)

Rapid Iron(III)−Fluoride‐Mediated Hydrogen Atom Transfer
por: Panda, Chakadola, et al.
Publicado: (2021)

Hydrogen Atom Transfer Driven Enantioselective Minisci Reaction of Alcohols
por: Colgan, Avene C., et al.
Publicado: (2022)

Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence
por: Etherington, Marc K., et al.
Publicado: (2016)

Analysis of vibronic coupling in a 4f molecular magnet with FIRMS
por: Kragskow, Jon G. C., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_7vmv1133q1g5fceo0pl6u0loi6