A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel–iron–hydride in [NiFe] hydrogenase

Direct spectroscopic evidence for a hydride bridge in the Ni–R form of [NiFe] hydrogenase has been obtained using iron-specific nuclear resonance vibrational spectroscopy (NRVS). The Ni–H–Fe wag mode at 675 cm(−1) is the first spectroscopic evidence for a bridging hydride in Ni–R as well as the firs...

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Detalles Bibliográficos
Autores principales: Wang, Hongxin, Yoda, Yoshitaka, Ogata, Hideaki, Tanaka, Yoshihito, Lubitz, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Feature Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629863/
https://www.ncbi.nlm.nih.gov/pubmed/26524296
http://dx.doi.org/10.1107/S1600577515017816

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4629863/
https://www.ncbi.nlm.nih.gov/pubmed/26524296
http://dx.doi.org/10.1107/S1600577515017816

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