Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2'-bipyridine

Group 13 M(I) compounds often disproportionate into M(0) and M(III). Here, however, we show that the reaction of the M(I) salt of the weakly coordinating alkoxyaluminate [Ga(I)(C(6)H(5)F)(2)](+)[Al(OR(F))(4)](−) (R(F)=C(CF(3))(3)) with 2,2'-bipyridine (bipy) yields the paramagnetic and distorte...

Descripción completa

Detalles Bibliográficos
Autores principales: Lichtenthaler, Martin R., Stahl, Florian, Kratzert, Daniel, Heidinger, Lorenz, Schleicher, Erik, Hamann, Julian, Himmel, Daniel, Weber, Stefan, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4633986/
https://www.ncbi.nlm.nih.gov/pubmed/26478464
http://dx.doi.org/10.1038/ncomms9288

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4633986/
https://www.ncbi.nlm.nih.gov/pubmed/26478464
http://dx.doi.org/10.1038/ncomms9288

Ejemplares similares