Cargando…
Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2'-bipyridine
Group 13 M(I) compounds often disproportionate into M(0) and M(III). Here, however, we show that the reaction of the M(I) salt of the weakly coordinating alkoxyaluminate [Ga(I)(C(6)H(5)F)(2)](+)[Al(OR(F))(4)](−) (R(F)=C(CF(3))(3)) with 2,2'-bipyridine (bipy) yields the paramagnetic and distorte...
| Autores principales: | , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Pub. Group
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4633986/ https://www.ncbi.nlm.nih.gov/pubmed/26478464 http://dx.doi.org/10.1038/ncomms9288 |