Metallocene Catalytic Insertion Polymerization of 1-Silene to Polycarbosilanes

Metallocene of zirconium were used as a catalyst for an insertion polymerization of 1-methylsilene directly into pre-ceramic precursor polyzirconocenecarbosilane (PZCS) during dechlorination of dichlorodimethylesilane by sodium, which exhibits high catalytic effectiveness with the maximum conversion...

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Detalles Bibliográficos
Autores principales: Tian, Yuelong, Ge, Min, Zhang, Weigang, Lv, Xiaoxu, Yu, Shouquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4635340/
https://www.ncbi.nlm.nih.gov/pubmed/26541636
http://dx.doi.org/10.1038/srep16274

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4635340/
https://www.ncbi.nlm.nih.gov/pubmed/26541636
http://dx.doi.org/10.1038/srep16274

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