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Tuning Coordination in s-Block Carbazol-9-yl Complexes

1,3,6,8-Tetra-tert-butylcarbazol-9-yl and 1,8-diaryl-3,6-di(tert-butyl)carbazol-9-yl ligands have been utilized in the synthesis of potassium and magnesium complexes. The potassium complexes (1,3,6,8-tBu(4)carb)K(THF)(4) (1; carb=C(12)H(4)N), [(1,8-Xyl(2)-3,6-tBu(2)carb)K(THF)](2) (2; Xyl=3,5-Me(2)C...

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Detalles Bibliográficos
Autores principales: Ortu, Fabrizio, Moxey, Graeme J, Blake, Alexander J, Lewis, William, Kays, Deborah L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4641456/
https://www.ncbi.nlm.nih.gov/pubmed/25783772
http://dx.doi.org/10.1002/chem.201406490