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Coordination Polymer Flexibility Leads to Polymorphism and Enables a Crystalline Solid–Vapour Reaction: A Multi-technique Mechanistic Study
Despite an absence of conventional porosity, the 1D coordination polymer [Ag(4)(O(2)C(CF(2))(2)CF(3))(4)(TMP)(3)] (1; TMP=tetramethylpyrazine) can absorb small alcohols from the vapour phase, which insert into Ag–O bonds to yield coordination polymers [Ag(4)(O(2)C(CF(2))(2)CF(3))(4)(TMP)(3)(ROH)(2)]...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4641464/ https://www.ncbi.nlm.nih.gov/pubmed/25962844 http://dx.doi.org/10.1002/chem.201500514 |