Turning Cucurbit[8]uril into a Supramolecular Nanoreactor for Asymmetric Catalysis

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Chiral macromolecules have been widely used as synthetic pockets to mimic natural enzymes and promote asymmetric reactions. An achiral host, cucurbit[8]uril (CB[8]), was used for an asymmetric Lewis acid catalyzed Diels–Alder reaction. We achieved a remarkable increase in enantioselectivity and a la...

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Detalles Bibliográficos
Autores principales: Zheng, Lifei, Sonzini, Silvia, Ambarwati, Masyitha, Rosta, Edina, Scherman, Oren A, Herrmann, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4643185/
https://www.ncbi.nlm.nih.gov/pubmed/26383272
http://dx.doi.org/10.1002/anie.201505628

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4643185/
https://www.ncbi.nlm.nih.gov/pubmed/26383272
http://dx.doi.org/10.1002/anie.201505628

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