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Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding

A triethylaluminium(TEAl)-modified Phillips ethylene polymerisation Cr/Ti/SiO(2) catalyst has been developed with two distinct active regions positioned respectively in the inner core and outer shell of the catalyst particle. DRIFTS, EPR, UV-Vis-NIR DRS, STXM, SEM-EDX and GPC-IR studies revealed tha...

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Detalles Bibliográficos
Autores principales: Cicmil, Dimitrije, Meeuwissen, Jurjen, Vantomme, Aurélien, Wang, Jian, van Ravenhorst, Ilse K, van der Bij, Hendrik E, Muñoz-Murillo, Ara, Weckhuysen, Bert M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4643190/
https://www.ncbi.nlm.nih.gov/pubmed/26349452
http://dx.doi.org/10.1002/anie.201506718