Crystal structure of 2α-(1,1-di­phenyl­eth­yl)-4-methyl-4α,5α-diphenyl-1,3-dioxolane: the result of a non-acid pinacol rearrangement

The title compound, C(30)H(28)O(2), was obtained during recrystallization of (±)-1,2-diphenyl-1,2-propane­diol in 1-butanol, from an unexpected non-acid-catalyzed pinacol rearrangement followed by acetal formation of the newly formed aldehyde with the diol. The tri-substituted dioxolane ring has a t...

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Detalles Bibliográficos
Autores principales: Kirchner, Richard M., Corfield, Peter W. R., Annabi, Michelle, Regan, John, Speina, Kevin, DiProperzio, Anthony, Ciaccio, James A., Capitani, Joseph F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645051/
https://www.ncbi.nlm.nih.gov/pubmed/26594491
http://dx.doi.org/10.1107/S2056989015017752

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645051/
https://www.ncbi.nlm.nih.gov/pubmed/26594491
http://dx.doi.org/10.1107/S2056989015017752

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