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Crystal structure of [Co(NH(3))(6)][Co(CO)(4)](2)

Hexaamminecobalt(II) bis­[tetra­carbonyl­cobaltate(-I)], [Co(NH(3))(6)][Co(CO)(4)](2), was synthesized by reaction of liquid ammonia with Co(2)(CO)(8). The Co(II) atom is coordinated by six ammine ligands. The resulting polyhedron, the hexa­amminecobalt(II) cation, exhibits point group symmetry -3....

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Detalles Bibliográficos
Autores principales: Müller, Thomas G., Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645071/
https://www.ncbi.nlm.nih.gov/pubmed/26594524
http://dx.doi.org/10.1107/S2056989015020290