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Crystal structures of two unusual, high oxidation state, 16-electron irida­benzenes

Treatment of carbon­yl(1,2-diphenylpenta-1,3-dien-1-yl-5-yl­idene)bis­(tri­phenyl­phosphane)iridium, [IrCO(—C(Ph)=C(Ph)—CH=CH—CH=)(PPh(3))(2)], with either bromine or iodine produced di­bromido­(1,2-diphenylpenta-1,3-dien-1-yl-5-yl­idene)(tri­phenyl­phosphine)iridium(III), [IrBr(2){—C(Ph)=C(Ph)—CH=C...

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Detalles Bibliográficos
Autores principales: Chase, Daniel T., Zakharov, Lev N., Haley, Michael M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645090/
https://www.ncbi.nlm.nih.gov/pubmed/26594499
http://dx.doi.org/10.1107/S2056989015018952