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Gold tetrahedra coil up: Kekulé-like and double helical superstructures

Magic-sized clusters, as the intermediate state between molecules and nanoparticles, exhibit critical transitions of structures and material properties. We report two unique structures of gold clusters solved by x-ray crystallography, including Au(40) and Au(52) protected by thiolates. The Au(40) an...

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Detalles Bibliográficos
Autores principales: Zeng, Chenjie, Chen, Yuxiang, Liu, Chong, Nobusada, Katsuyuki, Rosi, Nathaniel L., Jin, Rongchao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4646800/
https://www.ncbi.nlm.nih.gov/pubmed/26601286
http://dx.doi.org/10.1126/sciadv.1500425