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Gold(III)-CO and gold(III)-CO(2) complexes and their role in the water-gas shift reaction

The water-gas shift (WGS) reaction is an important process for the generation of hydrogen. Heterogeneous gold catalysts exhibit good WGS activity, but the nature of the active site, the oxidation state, and competing reaction mechanisms are very much matters of debate. Homogeneous gold WGS systems t...

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Detalles Bibliográficos
Autores principales: Roşca, Dragoş-Adrian, Fernandez-Cestau, Julio, Morris, James, Wright, Joseph A., Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4646827/
https://www.ncbi.nlm.nih.gov/pubmed/26601313
http://dx.doi.org/10.1126/sciadv.1500761