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Kumada–Grignard-type biaryl couplings on water

Well-established, traditional Kumada cross-couplings involve preformed Grignard reagents in dry ethereal solvent that typically react, e.g., with aryl halides via Pd catalysis to afford products of net substitution. Therefore, in the work described, which appears to be counterintuitive, exposure of...

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Detalles Bibliográficos
Autores principales: Bhattacharjya, Anish, Klumphu, Piyatida, Lipshutz, Bruce H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647940/
https://www.ncbi.nlm.nih.gov/pubmed/26084774
http://dx.doi.org/10.1038/ncomms8401