Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH(2): A Route to Poly(alkylphosphinoboranes)

Mild thermolysis of Lewis base stabilized phosphinoborane monomers R(1)R(2)P–BH(2)⋅NMe(3) (R(1),R(2)=H, Ph, or tBu/H) at room temperature to 100 °C provides a convenient new route to oligo- and polyphosphinoboranes [R(1)R(2)P-BH(2)](n). The polymerization appears to proceed via the addition/head-to-...

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Detalles Bibliográficos
Autores principales: Marquardt, Christian, Jurca, Titel, Schwan, Karl-Christian, Stauber, Andreas, Virovets, Alexander V, Whittell, George R, Manners, Ian, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648028/
https://www.ncbi.nlm.nih.gov/pubmed/26427911
http://dx.doi.org/10.1002/anie.201507084

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648028/
https://www.ncbi.nlm.nih.gov/pubmed/26427911
http://dx.doi.org/10.1002/anie.201507084

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