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Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH(2): A Route to Poly(alkylphosphinoboranes)
Mild thermolysis of Lewis base stabilized phosphinoborane monomers R(1)R(2)P–BH(2)⋅NMe(3) (R(1),R(2)=H, Ph, or tBu/H) at room temperature to 100 °C provides a convenient new route to oligo- and polyphosphinoboranes [R(1)R(2)P-BH(2)](n). The polymerization appears to proceed via the addition/head-to-...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648028/ https://www.ncbi.nlm.nih.gov/pubmed/26427911 http://dx.doi.org/10.1002/anie.201507084 |