E–H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

The synthesis of a phosphorus(III) compound bearing a N,N-bis(3,5-di-tert-butyl-2-phenoxy)amide ligand is reported. This species has been found to react with ammonia and water, activating the E–H bonds in both substrates by formal oxidative addition to afford the corresponding phosphorus(V) compound...

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Detalles Bibliográficos
Autores principales: Robinson, Thomas P, De Rosa, Daniel M, Aldridge, Simon, Goicoechea, Jose M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648037/
https://www.ncbi.nlm.nih.gov/pubmed/26404498
http://dx.doi.org/10.1002/anie.201506998

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648037/
https://www.ncbi.nlm.nih.gov/pubmed/26404498
http://dx.doi.org/10.1002/anie.201506998

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