Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C–H Functionalization and Spiroannulation

Chiral cyclopentadienyl rhodium complexes promote highly enantioselective enol-directed C(sp(2))-H functionalization and oxidative annulation with alkynes to give spiroindenes containing all-carbon quaternary stereocenters. High selectivity between two possible directing groups, as well as control o...

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Detalles Bibliográficos
Autores principales: Reddy Chidipudi, Suresh, Burns, David J, Khan, Imtiaz, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648053/
https://www.ncbi.nlm.nih.gov/pubmed/26404643
http://dx.doi.org/10.1002/anie.201507029

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648053/
https://www.ncbi.nlm.nih.gov/pubmed/26404643
http://dx.doi.org/10.1002/anie.201507029

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