Synthesis, Photochemical, and Redox Properties of Gold(I) and Gold(III) Pincer Complexes Incorporating a 2,2′:6′,2″-Terpyridine Ligand Framework

[Image: see text] Reaction of [Au(C(6)F(5))(tht)] (tht = tetrahydrothiophene) with 2,2′:6′,2″-terpyridine (terpy) leads to complex [Au(C(6)F(5))(η(1)-terpy)] (1). The chemical oxidation of complex (1) with 2 equiv of [N(C(6)H(4)Br-4)(3)](PF(6)) or using electrosynthetic techniques affords the Au(III...

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Detalles Bibliográficos
Autores principales: Gimeno, M. Concepción, López-de-Luzuriaga, José M., Manso, Elena, Monge, Miguel, Olmos, M. Elena, Rodríguez-Castillo, María, Tena, María-Teresa, Day, David P., Lawrence, Elliot J., Wildgoose, Gregory G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4649797/
https://www.ncbi.nlm.nih.gov/pubmed/26496068
http://dx.doi.org/10.1021/acs.inorgchem.5b01477

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4649797/
https://www.ncbi.nlm.nih.gov/pubmed/26496068
http://dx.doi.org/10.1021/acs.inorgchem.5b01477

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