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Reaction of allene esters with Selectfluor/TMSX (X = I, Br, Cl) and Selectfluor/NH(4)SCN: Competing oxidative/electrophilic dihalogenation and nucleophilic/conjugate addition
Reaction of benzyl and ethyl allenoates with TMSX (X = I, Br, Cl) and with NH(4)SCN were investigated in MeCN, DMF, and in imidazolium ionic liquids [BMIM][NTf(2)] and [BMIM][PF(6)] as solvent, in the presence and absence of Selectfluor. Comparative product analysis studies demonstrate that the abil...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660907/ https://www.ncbi.nlm.nih.gov/pubmed/26664584 http://dx.doi.org/10.3762/bjoc.11.180 |