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SmI(2)-mediated dimerization of indolylbutenones and synthesis of the myxobacterial natural product indiacen B

The synthesis and reactivity of indole derivatives substituted in the benzene section was studied. Starting materials 4- and 6-iodoindole were conveniently prepared via the Batcho–Leimgruber route and purified by sublimation. Novel vicinally indolyl-substituted cyclopentanols with unexpected cis-con...

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Detalles Bibliográficos
Autores principales: Marsch, Nils, Jones, Peter G, Lindel, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660955/
https://www.ncbi.nlm.nih.gov/pubmed/26664588
http://dx.doi.org/10.3762/bjoc.11.184