Hexacoordinate Ru-based olefin metathesis catalysts with pH-responsive N-heterocyclic carbene (NHC) and N-donor ligands for ROMP reactions in non-aqueous, aqueous and emulsion conditions

Three new ruthenium alkylidene complexes (PCy(3))Cl(2)(H(2)ITap)Ru=CHSPh (9), (DMAP)(2)Cl(2)(H(2)ITap)Ru=CHPh (11) and (DMAP)(2)Cl(2)(H(2)ITap)Ru=CHSPh (12) have been synthesized bearing the pH-responsive H(2)ITap ligand (H(2)ITap = 1,3-bis(2’,6’-dimethyl-4’-dimethylaminophenyl)-4,5-dihydroimidazol-...

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Detalles Bibliográficos
Autores principales: Balof, Shawna L, Nix, K Owen, Olliff, Matthew S, Roessler, Sarah E, Saha, Arpita, Müller, Kevin B, Behrens, Ulrich, Valente, Edward J, Schanz, Hans-Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660970/
https://www.ncbi.nlm.nih.gov/pubmed/26664616
http://dx.doi.org/10.3762/bjoc.11.212

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660970/
https://www.ncbi.nlm.nih.gov/pubmed/26664616
http://dx.doi.org/10.3762/bjoc.11.212

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