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Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp(2))–H bond arylations

We report herein a two or three step synthesis of fluorinated π-conjugated oligomers through iterative C–H bond arylations. Palladium-catalyzed desulfitative arylation of heteroarenes allowed in a first step the synthesis of fluoroaryl-heteroarene units in high yields. Then, the next steps involve d...

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Detalles Bibliográficos
Autores principales: Abdelmalek, Fatiha, Derridj, Fazia, Djebbar, Safia, Soulé, Jean-François, Doucet, Henri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661000/
https://www.ncbi.nlm.nih.gov/pubmed/26664622
http://dx.doi.org/10.3762/bjoc.11.218