Stereochemistry of ring-opening/cross metathesis reactions of exo- and endo-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitriles with allyl alcohol and allyl acetate

The ROCM reactions of exo- and endo-2-cyano-7-oxanorbornenes with allyl alcohol or allyl acetate promoted by different ruthenium alkylidene catalysts were studied. The stereochemical outcome of the reactions was established. The issues concerning chemo- (ROCM vs ROMP), regio- (1-2- vs 1-3-product fo...

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Detalles Bibliográficos
Autores principales: Wałejko, Piotr, Dąbrowski, Michał, Szczepaniak, Lech, Morzycki, Jacek W, Witkowski, Stanisław
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661012/
https://www.ncbi.nlm.nih.gov/pubmed/26664608
http://dx.doi.org/10.3762/bjoc.11.204

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661012/
https://www.ncbi.nlm.nih.gov/pubmed/26664608
http://dx.doi.org/10.3762/bjoc.11.204

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