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Chiral Cu(II)-catalyzed enantioselective β-borylation of α,β-unsaturated nitriles in water
The promising performance of copper(II) complexes was demonstrated for asymmetric boron conjugate addition to α,β-unsaturated nitriles in water. The catalyst system, which consisted of Cu(OAc)(2) and a chiral 2,2′-bipyridine ligand, enabled β-borylation and chiral induction in water. Subsequent prot...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661013/ https://www.ncbi.nlm.nih.gov/pubmed/26664621 http://dx.doi.org/10.3762/bjoc.11.217 |