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Chiral Cu(II)-catalyzed enantioselective β-borylation of α,β-unsaturated nitriles in water

The promising performance of copper(II) complexes was demonstrated for asymmetric boron conjugate addition to α,β-unsaturated nitriles in water. The catalyst system, which consisted of Cu(OAc)(2) and a chiral 2,2′-bipyridine ligand, enabled β-borylation and chiral induction in water. Subsequent prot...

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Detalles Bibliográficos
Autores principales:	Zhu, Lei, Kitanosono, Taku, Xu, Pengyu, Kobayashi, Shū
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661013/ https://www.ncbi.nlm.nih.gov/pubmed/26664621 http://dx.doi.org/10.3762/bjoc.11.217

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