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Mechanism, kinetics and selectivity of selenocyclization of 5-alkenylhydantoins: an experimental and computational study
The mechanism and selectivity of a bicyclic hydantoin formation by selenium-induced cyclization are investigated. The proposed mechanism involves the intermediates formed by an electrophilic addition of the selenium reagent on a double bond of the starting 5-alkenylhydantoin prior the cyclization. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661018/ https://www.ncbi.nlm.nih.gov/pubmed/26664604 http://dx.doi.org/10.3762/bjoc.11.200 |