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Mechanism, kinetics and selectivity of selenocyclization of 5-alkenylhydantoins: an experimental and computational study

The mechanism and selectivity of a bicyclic hydantoin formation by selenium-induced cyclization are investigated. The proposed mechanism involves the intermediates formed by an electrophilic addition of the selenium reagent on a double bond of the starting 5-alkenylhydantoin prior the cyclization. T...

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Detalles Bibliográficos
Autores principales: Šmit, Biljana M, Pavlović, Radoslav Z, Milenković, Dejan A, Marković, Zoran S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661018/
https://www.ncbi.nlm.nih.gov/pubmed/26664604
http://dx.doi.org/10.3762/bjoc.11.200