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Copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines

We report herein studies on copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines. Treatment of N–H ketimines having an α-sp(3) hybridized carbon under Cu-catalyzed aerobic reaction conditions resulted in a radical fragmentation with C–C bond cleavage to give the corresponding carbonit...

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Detalles Bibliográficos
Autores principales: Tnay, Ya Lin, Ang, Gim Yean, Chiba, Shunsuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661020/
https://www.ncbi.nlm.nih.gov/pubmed/26664613
http://dx.doi.org/10.3762/bjoc.11.209