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Assembling an alkyl rotor to access abrupt and reversible crystalline deformation of a cobalt(II) complex
Harnessing molecular motion to reversibly control macroscopic properties, such as shape and size, is a fascinating and challenging subject in materials science. Here we design a crystalline cobalt(II) complex with an n-butyl group on its ligands, which exhibits a reversible crystal deformation at a...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Pub. Group
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4667628/ https://www.ncbi.nlm.nih.gov/pubmed/26531811 http://dx.doi.org/10.1038/ncomms9810 |