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Yttrium Complexes of Arsine, Arsenide, and Arsinidene Ligands**
Deprotonation of the yttrium–arsine complex [Cp′(3)Y{As(H)(2)Mes}] (1) (Cp′=η(5)-C(5)H(4)Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′(2)Y[μ-As(H)Mes]}(3)] (2). Deprotonation of the As–H bonds in 2 by nBuLi produces [Li(thf)(4)](2)[{Cp′(2)Y(μ(3)-AsMes)}(3)Li], [Li(thf)(4)](2)[3], i...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4672686/ https://www.ncbi.nlm.nih.gov/pubmed/25655652 http://dx.doi.org/10.1002/anie.201500173 |