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Yttrium Complexes of Arsine, Arsenide, and Arsinidene Ligands**

Deprotonation of the yttrium–arsine complex [Cp′(3)Y{As(H)(2)Mes}] (1) (Cp′=η(5)-C(5)H(4)Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′(2)Y[μ-As(H)Mes]}(3)] (2). Deprotonation of the As–H bonds in 2 by nBuLi produces [Li(thf)(4)](2)[{Cp′(2)Y(μ(3)-AsMes)}(3)Li], [Li(thf)(4)](2)[3], i...

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Detalles Bibliográficos
Autores principales: Pugh, Thomas, Kerridge, Andrew, Layfield, Richard A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4672686/
https://www.ncbi.nlm.nih.gov/pubmed/25655652
http://dx.doi.org/10.1002/anie.201500173