The Fe–V Cofactor of Vanadium Nitrogenase Contains an Interstitial Carbon Atom

The first direct evidence is provided for the presence of an interstitial carbide in the Fe–V cofactor of Azotobacter vinelandii vanadium nitrogenase. As for our identification of the central carbide in the Fe–Mo cofactor, we employed Fe Kβ valence-to-core X-ray emission spectroscopy and density fun...

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Detalles Bibliográficos
Autores principales: Rees, Julian A, Bjornsson, Ragnar, Schlesier, Julia, Sippel, Daniel, Einsle, Oliver, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675075/
https://www.ncbi.nlm.nih.gov/pubmed/26376620
http://dx.doi.org/10.1002/anie.201505930

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675075/
https://www.ncbi.nlm.nih.gov/pubmed/26376620
http://dx.doi.org/10.1002/anie.201505930

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