Presolvated Electron Reactions with Methyl Acetoacetate: Electron Localization, Proton-Deuteron Exchange, and H-Atom Abstraction

Radiation-produced electrons initiate various reaction processes that are important to radiation damage to biomolecules. In this work, the site of attachment of the prehydrated electrons with methyl acetoacetate (MAA, CH(3)-CO-CH(2)-COOCH(3)) at 77 K and subsequent reactions of the anion radical (CH...

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Detalles Bibliográficos
Autores principales: Petrovici, Alex, Adhikary, Amitava, Kumar, Anil, Sevilla, Michael D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678098/
https://www.ncbi.nlm.nih.gov/pubmed/25255751
http://dx.doi.org/10.3390/molecules190913486

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678098/
https://www.ncbi.nlm.nih.gov/pubmed/25255751
http://dx.doi.org/10.3390/molecules190913486

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