A Stimuli-Responsive Rotaxane–Gold Catalyst: Regulation of Activity and Diastereoselectivity

A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the identity of which significantly influences both the yield and diastereoselectivity of the reac...

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Detalles Bibliográficos
Autores principales: Galli, Marzia, Lewis, James E M, Goldup, Stephen M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678423/
https://www.ncbi.nlm.nih.gov/pubmed/26387887
http://dx.doi.org/10.1002/anie.201505464

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678423/
https://www.ncbi.nlm.nih.gov/pubmed/26387887
http://dx.doi.org/10.1002/anie.201505464

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