Ligand-Mediated and Copper-Catalyzed C(sp(3))-H Bond Functionalization of Aryl Ketones with Sodium Sulfinates under Mild Conditions

A novel and convenient copper (II) bromide and 1,8-diazabicyclo[5.4.1]undec-7-ene (DBU) or 1,10-phenanthroline catalysis protocol for the construction of α-alkyl-β-keto sulfones via C(sp(3))-H bond functionalization followed by C(sp(3))-S bond formation between aryl ketones and sodium sulfinates at...

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Detalles Bibliográficos
Autores principales: Lan, Xing-Wang, Wang, Nai-Xing, Bai, Cui-Bing, Zhang, Wei, Xing, Yalan, Wen, Jia-Long, Wang, Yan-Jing, Li, Yi-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4683520/
https://www.ncbi.nlm.nih.gov/pubmed/26681470
http://dx.doi.org/10.1038/srep18391

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4683520/
https://www.ncbi.nlm.nih.gov/pubmed/26681470
http://dx.doi.org/10.1038/srep18391

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