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Copper-catalyzed arylation of alkyl halides with arylaluminum reagents

We report a Cu-catalyzed coupling between triarylaluminum reagents and alkyl halides to form arylalkanes. The reaction proceeds in the presence of N,N,N’,N’-tetramethyl-o-phenylenediamine (NN-1) as a ligand in combination with CuI as a catalyst. This catalyst system enables the coupling of primary a...

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Detalles Bibliográficos
Autores principales: Shrestha, Bijay, Giri, Ramesh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4685909/
https://www.ncbi.nlm.nih.gov/pubmed/26734088
http://dx.doi.org/10.3762/bjoc.11.261