Unexpected formation of N′-phenyl-thiophosphorohydrazidic acid O,S-dimethyl ester from acephate: chemical, biotechnical and computational study

By the nucleophilic attack of phenylhydrazine on acephate in aqueous medium, a stable product N′-phenyl-thiophosphorohydrazidic acid O,S-dimethyl ester (1) was obtained and characterized by elemental, spectral and thermal analysis. Thermodynamic parameters, Ea, ΔH°, ΔS° and ΔG°, have found to be 62....

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Detalles Bibliográficos
Autores principales: Kumar, Vijay, Kaur, Sukhmanpreet, Singh, Simranjeet, Upadhyay, Niraj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2015
Materias:
Original Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689696/
https://www.ncbi.nlm.nih.gov/pubmed/28330071
http://dx.doi.org/10.1007/s13205-015-0313-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689696/
https://www.ncbi.nlm.nih.gov/pubmed/28330071
http://dx.doi.org/10.1007/s13205-015-0313-6

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