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Alkynylation of Thiols with Ethynylbenziodoxolone (EBX) Reagents: α- or β- π-Addition?

[Image: see text] The alkynylation of thiols with EthynylBenziodoXolone (EBX) reagents is a fast and chemoselective method for the synthesis of thioalkynes. Combined experimental and computational studies are reported, which led to the identification of a new mechanism for this reaction, proceeding...

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Detalles Bibliográficos
Autores principales: Wodrich, Matthew D., Caramenti, Paola, Waser, Jerome
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4700532/
https://www.ncbi.nlm.nih.gov/pubmed/26652212
http://dx.doi.org/10.1021/acs.orglett.5b03241