Crystal structure of K(0.75)[Fe(II) (3.75)Fe(III) (1.25)(HPO(3))(6)]·0.5H(2)O, an open-framework iron phosphite with mixed-valent Fe(II)/Fe(III) ions

Single crystals of the title compound, potassium hexa­phosphito­penta­ferrate(II,III) hemihydrate, K(0.75)[Fe(II) (3.75)Fe(III) (1.25)(HPO(3))(6)]·0.5H(2)O, were grown under mild hydro­thermal conditions. The crystal structure is isotypic with Li(1.43)[Fe(II) (4.43)Fe(III) (0.57)(HPO(3))(6)]·1.5H(2)...

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Detalles Bibliográficos
Autores principales: Larrea, Edurne S., Mesa, José Luis, Legarra, Estibaliz, Aguayo, Andrés Tomás, Arriortua, Maria Isabel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704752/
https://www.ncbi.nlm.nih.gov/pubmed/26870587
http://dx.doi.org/10.1107/S2056989015024007

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704752/
https://www.ncbi.nlm.nih.gov/pubmed/26870587
http://dx.doi.org/10.1107/S2056989015024007

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