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Crystal structure of K(0.75)[Fe(II) (3.75)Fe(III) (1.25)(HPO(3))(6)]·0.5H(2)O, an open-framework iron phosphite with mixed-valent Fe(II)/Fe(III) ions
Single crystals of the title compound, potassium hexaphosphitopentaferrate(II,III) hemihydrate, K(0.75)[Fe(II) (3.75)Fe(III) (1.25)(HPO(3))(6)]·0.5H(2)O, were grown under mild hydrothermal conditions. The crystal structure is isotypic with Li(1.43)[Fe(II) (4.43)Fe(III) (0.57)(HPO(3))(6)]·1.5H(2)...
Autores principales: | Larrea, Edurne S., Mesa, José Luis, Legarra, Estibaliz, Aguayo, Andrés Tomás, Arriortua, Maria Isabel |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704752/ https://www.ncbi.nlm.nih.gov/pubmed/26870587 http://dx.doi.org/10.1107/S2056989015024007 |
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