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Photooxidation and photoaquation of iron hexacyanide in aqueous solution: A picosecond X-ray absorption study

We present a picosecond Fe K-edge absorption study of photoexcited ferrous and ferric hexacyanide in water under 355 and 266 nm excitation. Following 355 nm excitation, the transient spectra for the ferrous and ferric complexes exhibit a red shift of the edge reflecting an increased electron density...

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Detalles Bibliográficos
Autores principales: Reinhard, M., Penfold, T. J., Lima, F. A., Rittmann, J., Rittmann-Frank, M. H., Abela, R., Tavernelli, I., Rothlisberger, U., Milne, C. J., Chergui, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4711601/
https://www.ncbi.nlm.nih.gov/pubmed/26798775
http://dx.doi.org/10.1063/1.4871751