The crystal structures of tetra­kis­(μ-n-butyrato-κ(2) O:O′)bis[bromidorhenium(III)] and tetra­kis­(μ-n-butyrato-κ(2) O:O′)bis[chlorido­rhenium(III)] aceto­nitrile disolvate

The title complexes, [Re(2)Br(2)(O(2)CC(3)H(7))(4)], (1), and [Re(2)(O(2)CC(3)H(7))(4)Cl(2)]·2CH(3)CN, (2), both exhibit paddlewheel structures with four carboxyl­ate ligands bridging two Re(III) atoms. The Re—Re distances are 2.2325 (2) and 2.2299 (3) Å, indicating quadruple bonds between the Re(II...

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Detalles Bibliográficos
Autores principales: Reed, Carly R., Brennessel, William W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719818/
https://www.ncbi.nlm.nih.gov/pubmed/26870409
http://dx.doi.org/10.1107/S2056989015020563

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719818/
https://www.ncbi.nlm.nih.gov/pubmed/26870409
http://dx.doi.org/10.1107/S2056989015020563

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