Crystal structures of tris­[1-oxo­pyridine-2-olato(1−)]silicon(IV) chloride chloro­form-d (1) disolvate, tris­[1-oxo­pyridine-2-olato(1−)]silicon(IV) chloride aceto­nitrile unqu­anti­fied solvate, and fac-tris­[1-oxo­pyridine-2-thiol­ato(1−)]silicon(IV) chloride chloro­form-d (1) disolvate

The cations in the title salts, [Si(OPO)(3)]Cl·2CDCl(3), (I), [Si(OPO)(3)]Cl·xCH(3)CN, (II), and fac-[Si(OPTO)(3)]Cl·2CDCl(3), (III) (OPO = 1-oxo-2-pyridin­one, C(5)H(4)NO(2), and OPTO = 1-oxo-2-pyridine­thione, C(5)H(4)NOS), have distorted octa­hedral coordination spheres. The first two structures...

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Detalles Bibliográficos
Autores principales: Kraft, Bradley M., Brennessel, William W., Ryan, Amy E., Benjamin, Candace K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719831/
https://www.ncbi.nlm.nih.gov/pubmed/26870422
http://dx.doi.org/10.1107/S2056989015022203

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719831/
https://www.ncbi.nlm.nih.gov/pubmed/26870422
http://dx.doi.org/10.1107/S2056989015022203

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