Crystal structure of 2-bromo-3-di­methyl­amino-N,N,N′,N′,4-penta­methyl-4-(tri­methyl­sil­yloxy)pent-2-eneamidinium bromide

The reaction of the ortho­amide 1,1,1-tris­(di­methyl­amino)-4-methyl-4-(tri­methyl­sil­yloxy)pent-2-yne with bromine in benzene, yields the title salt, C(15)H(33)BrN(3)OSi(+)·Br(−). The C—N bond lengths in the amidinium unit are 1.319 (6) and 1.333 (6) Å, indicating double-bond character, pointing...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Kress, Ralf, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719979/
https://www.ncbi.nlm.nih.gov/pubmed/26870498
http://dx.doi.org/10.1107/S205698901502383X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719979/
https://www.ncbi.nlm.nih.gov/pubmed/26870498
http://dx.doi.org/10.1107/S205698901502383X

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