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Thioamination of Alkenes with Hypervalent Iodine Reagents

An efficient thioamination of alkenes mediated by iodine(III) reagents is described. The use of different sulfur nucleophiles allows the flexible synthesis of 1,2-aminothiols from alkenes. By employing chiral iodine(III) reagents, a stereoselective version of the thioamination protocol has also been...

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Detalles Bibliográficos
Autores principales: Mizar, Pushpak, Niebuhr, Rebecca, Hutchings, Matthew, Farooq, Umar, Wirth, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley & Sons, Ltd 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4725223/
https://www.ncbi.nlm.nih.gov/pubmed/26660291
http://dx.doi.org/10.1002/chem.201504636